(OC-6-33)-(2,2′-Bipyridine-κ2 N,N′)trimethyl(2-methylsulfanyl-2-thiazoline-κN)platinum(IV) tetrafluoridoborate
نویسندگان
چکیده
The asymmetric unit of the title complex, [Pt(CH(3))(3)(C(10)H(8)N(2))(C(4)H(7)NS(2))]BF(4), contains two crystallographically independent mol-ecules. The Pt(IV) atom in each complex cation exhibits a distorted octa-hedral coordination geometry, built up by three methyl ligands in a facial binding fashion, a bipyridine ligand and a monodentately N-bound 2-methyl-sulfanyl-2-thia-zoline ligand (configuration index: OC-6-33). In the crystal structure, weak inter-molecular C-H⋯F hydrogen bonds are found between the complex cations and BF(4) (-) anions.
منابع مشابه
cis-Bis(acetonitrile-κN)bis(2,2′-bipyridine-κ2 N,N′)ruthenium(II) tetrafluoridoborate
In the cation of the title compound, [Ru(CH(3)CN)(2)(C(10)H(8)N(2))(2)](BF(4))(2), the Ru(II) atom is six-coordinated in a distorted octa-hedral geometry by the N atoms of the two 2,2'-bipyridine (bpy) ligands and two cis-arranged acetonitrile mol-ecules. The dihedral angles formed by the pyridine rings of the bpy ligands are 8.86 (12) and 10.12 (14)°. In the crystal, the cations and anions are...
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